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ZSM-22 (TON Framework): Applications, Advantages, and Future Availability

Views: 0     Author: QT     Publish Time: 2025-08-26      Origin: QT

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Among the family of synthetic zeolites, ZSM-22 (TON framework) occupies a unique niche. Unlike more widely known zeolites such as ZSM-5 or SSZ-13, ZSM-22 features a one-dimensional pore system with 10-membered ring channels (~0.52 × 0.45 nm), making it highly selective in catalytic reactions.




Structural Features of ZSM-22


  • Framework type: TON (International Zeolite Association classification).

  • Pore system: One-dimensional straight channels.

  • Si/Al ratio flexibility: Can be synthesized across a broad Si/Al range, affecting acidity and catalytic selectivity.

  • Crystal morphology: Needle-like crystals that can be shaped into extrudates or pellets for industrial reactors.




Key Applications in Industry


  1. Hydroisomerization of Linear Paraffins

    • ZSM-22 shows excellent selectivity for converting straight-chain hydrocarbons (C5–C7, C10–C14) into branched isomers, improving octane numbers in gasoline or enhancing cold-flow properties in diesel.

    • (Reference: B. C. Gates, “Catalytic Chemistry,” Wiley, 1992 – description of ZSM-22 activity in paraffin isomerization).


  2. Selective Cracking of Hydrocarbons

    • The narrow 1D channels suppress undesired secondary reactions, enabling higher yields of targeted olefins and lower coke formation compared to wider-pore zeolites.


  3. Aromatics Transformation & Alkylation

    • Used in para-xylene maximization and other petrochemical upgrading processes where shape selectivity is critical.




 Advantages of ZSM-22


  • Shape-selectivity: One-dimensional pores provide better control over product distribution.

  • Lower coke deposition: Compared with ZSM-5, ZSM-22 resists deactivation from coking under prolonged operation.

  • Thermal stability: Maintains crystallinity and catalytic activity at high reaction temperatures.

  • Flexibility: Can be tailored by adjusting Si/Al ratio and metal promoters (Pt, Pd, Ni).




Future Product Availability


At present, ZSM-22 is not yet listed in our standard product catalog. However, our technical team is preparing to launch ZSM-22 (TON) as a new product offering in the near future.


Once released, we will provide:

  • Full technical specifications (Si/Al ratio ranges, BET surface area, crystallinity data).

  • Particle size distributions and shaping options (powder, extrudates).

  • Detailed datasheets and application case studies.


Customers interested in early access or custom ZSM-22 development are welcome to contact us now, so we can provide updates once the product is officially available.




FAQ

Q1: How does ZSM-22 differ from ZSM-5?
ZSM-22 has a 1D channel structure, while ZSM-5 (MFI framework) has a 3D channel system. This difference leads to higher shape selectivity in ZSM-22 but lower diffusivity compared to ZSM-5.


Q2: Is ZSM-22 suitable for FCC or hydrocracking?
It can be used as an additive for hydroisomerization or selective cracking but is less common in FCC compared to ZSM-5.


Q3: When will your ZSM-22 be available?
We expect to release ZSM-22 with full specifications and datasheets soon. Customers can register interest now to receive technical documentation as soon as it is launched.


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Shandong Yutai is a premier producers of specialty zeolite powders and catalysts for petrolchemical and environmental applications
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